Georg Brandt | c. 1630 - c. 1710 |
Robert Wilhelm Bunsen | March 31st 1811 - August 16th 1899 |
When confronted by the vast array of apparatus used in chemistry lab, a student can usually identify with a high degree of confidence one of the more familiar pieces of equipment, the Bunsen burner. While this essential piece of laboratory equipment has immortalized the name of Robert Wilhelm Bunsen, it was not invented by him. Bunsen improved the burner's design to aid his endeavors in spectroscopy. Ironically, Bunsen will be remembered by generations of chemistry students for a mere improvement in a burner design, when his other contributions to the field of chemistry are vastly more significant and diverse, covering such areas as organic chemistry, arsenic compounds, gas measurements and analysis, the galvanic battery, elemental spectroscopy and geology. Bunsen was born on March 31, 1811 in Gottingen, Germany, the youngest of four sons. As his father was a professor of modern languages at the university, an academic environment would surround him from birth. After schooling in the city of Holzminden, Bunsen studied chemistry at Gottingen. Receiving his doctorate at age 19, Bunsen set off on extensive travels, partially underwritten by the government, that took him through Germany and Paris and eventually to Vienna from 1830 to 1833. During this time, Bunsen visited Henschel's machinery manufacturing plant and saw the "new small steam engine." In Berlin, he saw the mineralogical collections of Weiss and had contact with Runge, the discoverer of aniline. Continuing on his journeys, Bunsen met with Liebig in Giessen and with Mitscherlich in Bonn for a geological trip through the Eifel mountains. In Paris and Vienna, Bunsen visited the Sevres porcelain works and met with the outstanding chemists of the times. These travels allowed Bunsen the opportunity to establish a network of contacts that would stay with him throughout his illustrious career. | | Upon his return to Germany, Bunsen became a lecturer at Gottingen and began his experimental studies of the insolubility of metal salts of arsenious acid. His discovery of the use of iron oxide hydrate as a precipitating agent is still the best known antidote against arsenic poisoning to this day. This was his only venture in organic/physiological chemistry. | | In 1836, Bunsen was nominated to succeed Wöhler at Kassel. He taught there for two years before accepting a position at the University of Marsburg which was the site of his important and dangerous studies of cacodyl derivatives. This research was his only work in pure organic chemistry and made him immediately famous within the scientific community. Cacodyl (from the Greek kakodhs - "stinking") was also known as alkarsine or "Cadet's liquid," a product made from arsenic distilled with potassium acetate. The chemical composition of this liquid was unknown, but it and its compounds were known to be poisonous, highly flammable and had an extremely nauseating odour even in minute quantities. Bunsen himself described one of these compounds: "the smell of this body produces instantaneous tingling of the hands and feet, and even giddiness and insensibility... It is remarkable that when one is exposed to the smell of these compounds the tongue becomes covered with a black coating, even when no further evil effects are noticeable." Bunsen's daring experiments showed that cacodyl was an oxide of arsenic that contained a methyl radical (a group of atoms acting as one species). These results significantly furthered the earlier work by Gay-Lussac, who had isolated the radical cyan in 1815, and that of Liebig and Wöhler who published "One the radical of benzoic acid" in 1832. Typical of his research life, however, Bunsen seemed content to explore subjects of interest in his lab, but remained outside the fray that surrounded the often "violent" discussions of theoretical subjects. Although Bunsen's work brought him quick and wide acclaim, he nearly killed himself from arsenic poisoning and it also cost him the sight of one eye - an explosion of the compound sent a sliver of glass into his eye. Recovery was slow and painful. | | While at Marsburg, Bunsen studied blast furnaces and demonstrated that over half the heat was lost in the charcoal-burning German furnaces. In British furnaces, over 80% was lost. Bunsen and a collaborator, Lyon Playfair, suggested techniques that could recycle gases through the furnace and retrieve valuable escaping by-products such as ammonia. Other work during this period concentrated on technological experiments such as the generation of galvanic currents in batteries. In 1841, instead of the expensive platinum electrode used in Grove's battery, Bunsen made a carbon electrode. This led to large scale use of the "Bunsen battery" in the production of arc-light and in electroplating. | | One of the more memorable episodes during Bunsen's tenure at Marsburg was a geological trip to Iceland sponsored by the Danish government following the eruption of Mount Hekla in 1845. Indulging his lifelong interest in geology, Bunsen collected gases emitted from volcanic vents and performed extensive chemical analyses of volcanic rock. In addition to sampling lava gases, Bunsen investigated the theory of geyser action. The popular belief of his time was that the water from geysers was volcanic in origin. Bunsen took rocks from the area and boiled them in rain water. He found that the resulting solution was quite similar to geyser water. He conducted temperature studies on the water in the geyser tube at different depths and discovered that the water was indeed hot enough to boil. Due to pressure differentials caused by the moving column of water, boiling occurs in the middle of the tube and throws the mass of water above it into the sky above. In true investigative spirit Bunsen experimented with an artificial geyser in the lab: | | "To confirm his theory, Bunsen made an artificial geyser, consisting of a basin of water having a long tube extending below it. He heated the tube at the bottom andat about the middlepoint. As the water at the middle reached its boiling point, all of the phenomena of geyser action were beautifully shown, including the preliminary thundering. That was in 1846. From that day to this Bunsen's theory of geyser action has been generally accepted by geologists." In 1852 Bunsen succeeded Leopold Gmelin at Heidelberg. His stature was such that he attracted students and chemists from all over the world to study in his laboratory. Again, Bunsen ignored the current trend in organic chemistry which was fast overtaking the experimental world. Instead, Bunsen improved his earlier work on batteries: using chromic acid instead of nitric acid, he was able to produce pure metals such as chromium, magnesium, aluminum, manganese, sodium, barium, calcium and lithium by electrolysis. Bunsen devised a sensitive ice calorimeter that measured the volume rather than the mass of the ice melted. This allowed him to measure the metals' specific heat to find their true atomic weights. During this period, he also pressed magnesium into wire; the element came into general use as an outstanding illuminating agent. A former student of Bunsen's believes that it was this "splendid light" from the combustion of magnesium that led Bunsen to devote considerable attention to photochemical studies. A ten year collaboration with Sir Henry Roscoe began in 1852. They took equal volumes of gaseous hydrogen and chlorine and studied the formation of HCl, which occurs in specific relationship to the amount of light received. Their results showed that the light radiated from the sun per minute was equivalent to the chemical energy of 25 x 1012 mi3 of a hydrogen-chlorine mixture forming HCl. | | In 1859, Bunsen suddenly discontinued his work with Roscoe, telling him: | | At present Kirchhoff and I are engaged in a common work which doesn't let us sleep...Kirchhoff has made a wonderful, entirely unexpected discovery in finding the cause of the dark lines in the solar spectrum....thus a means has been found to determine the composition of the sun and fixed stars with the same accuracy as we determine sulfuric acid, chlorine, etc., with our chemical reagents. Substances on the earth can be determined by this method just as easily as on the sun, so that, for example, I have been able to detect lithium in twenty grams of sea water." Gustav Kirchhoff, a young Prussian physicist, had the brilliant insight to use a prism to separate the light into its constituent rays, instead of looking through coloured glass to distinguish between similarly coloured flames. Thus the fledgling science of spectroscopy, which would develop into a vital tool for chemical analysis, was born. In order to study the resultant spectra, however, a high temperature, nonluminous flame was necessary. An article published by Bunsen and Kirchhoff in 1860 states: | | "The lines show up the more distinctly the higher the temperature and the lower the luminescence of the flame itself. The gas burner described by one of us has a flame of very high temperature and little luminescence and is, therefore, particularly suitable for experiments on the bright lines that are characteristic for these substances." The burner described was quickly dubbed the "Bunsen burner," although the apparatus is not of his design. The concept to premix the gas and air prior to combustion in order to yield the necessary high temperature, nonluminous flame belongs to Bunsen. Credit for the actual design and manufacture of the burner goes to Peter Desaga, a technician at the University of Heidelburg. Within five years of the development of the burner, Bunsen and Kirchhoff were deeply involved with spectroscopy, inventing yet another instrument: the Bunsen-Kirchhoff spectroscope. This vital instrument of chemical analysis can trace its ancestry to such simple components as a "prism, a cigar box, and two ends of otherwise unusable old telescopes." From such humble beginnings came the instrument which proved to be of tremendous importance in chemical analysis and the discovery of new elements. | | In addition to yielding a unique spectrum for each element, the spectroscope had the advantage of definite identification while only using a minimal amount of sample, on the range of nanograms to micrograms for elements like sodium and barium respectively. Using the techniques they devised, Bunsen and Kirchhoff announced the discovery of caesium (Latin caesium, "sky blue") in the following passage: | | "Supported by unambiguous results of the spectral-analytical method, we believe we can state right now that there is a fourth metal in the alkali group besides potassium, sodium, and lithium, and it has a simple characteristic spectrum like lithium; a metal that shows only two lines in our apparatus: a faint blue one, almost coinciding with Srd, and another blue one a little further to the violet end of the spectrum and as strong and as clearly defined as the lithium line." Some of Bunsen's enthusiasm is readily apparent in a letter to Roscoe dated November 6, 1869: "I have been very fortunate with my new metal...I shall name it caesium because of its beautiful blue spectral line. Next Sunday I expect to find time to make the first determination of its atomic weight." In 1861, only a few months following their caesium discovery, Bunsen and Kirchhoff announced the discovery of yet another new alkali metal. Two hitherto undiscovered violet spectral lines in an alkali of the mineral lepidolite were attributed to a new element, rubidium (Latin rubidus, "darkest red colour"). Bunsen and Kirchhoff's combined genius quickly paved the way for others to claim elemental discoveries. The spectroscope served as a springboard by which five new elements were discovered. These included thallium (Crookes, 1861), indium (Reich and Richter, 1863), gallium (Lecoq de Boisbaudran, 1875), scandium (Nilson, 1879) and germanium (Winkler1886). Fittingly, Bunsen's original vision of analyzing the composition of the stars was realized in 1868 when helium was discovered in the solar spectrum. | | Throughout his professional life, Bunsen's personal life centered around his laboratory and his students. Never marrying, Bunsen often took on the introductory courses that were shunned by other colleagues. During the one hundred hours of lectures presented each semester, Bunsen emphasized experimentation and tabulated summaries and patiently introduced students to the world of analytical chemistry. Bunsen's habit was to assign a scientific task to his students and then to work with a student only as long as required to reach some measure of independence. Many principal players in the history of chemistry can trace their chemical roots back to Bunsen's laboratory. Two of his more famous students were Dmitri Mendeleev and Lothar Meyer. | | According to accounts, Bunsen was one of the more modest of giants: | | He never said: 'I have discovered,' or 'I found...' He was characterized by extraordinary, distinguished modesty. That does not mean that he was not conscious of his own value. He knew how to use it at the right time and in the right company; he even had a considerable degree of very sound egotism." The scientific world held Bunsen in high esteem for much of his long professional life. In 1842 he was elected to the Chemical Society of London and the Academie des Sciences in 1853. He was named a foreign fellow of the Royal Society of London in 1858, receiving its Copley Medal in 1860. Bunsen and Kirchhoff were recipients of the first Davy Medal in 1877. The Albert Medal was awarded in 1898 in recognition of Bunsen's many scientific contributions to industry. Of these honors, Bunsen once remarked, "Such things had value for me only because they pleased my mother; she is now dead." Upon his retirement at the age of 78, Bunsen left the chemical work behind, returned to his first love of geology, keeping up with the latest developments in the field and corresponding with his old friends such as Roscoe, Kirchhoff and Helmholtz. Bunsen died August 16, 1899 after a peaceful three day sleep, leaving behind a glowing legacy of discoveries and technological advances that allowed the world of chemistry to burn brightly. | |
Antoine Alexandre Brutus Bussy | (May 29th 1794 - February 1st 1882 |
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Henry Cavendish | October 10th 1731 - February 24ht 1810 |
Per Teodor Cleve | February 10th 1840 - June 18th 1905 |
Cleve, who was born in the Swedish capital Stockholm, became assistant professor of chemistry at the University of Uppsala in 1868 and was later made professor of general and agricultural chemistry there. He is mainly remembered for his work on the rare earth elements. | | In 1874 Cleve concluded that didymium was in fact two elements; this was proved in 1885 and the two elements named neodymium and praseodymium. In 1879 he showed that the element scandium, newly discovered by the Swedish chemist Lars Nilson (1840-1899), was in fact the eka-boron predicted by Dmitri Mendeleev in his periodic table. In the same year, working with a sample of erbia from which he had removed all traces of scandia and ytterbia, Cleve found two new earths, which he named holmium, after Stockholm, and thulium, after the old name for Scandinavia. holmium in fact turned out to be a mixture for, in 1886, Lecoq de Boisbaudran discovered that it also contained the new element dysprosium. | | Cleve is also remembered as the teacher of Svante Arrhenius. | |
He was the eighth president of Cornell University. He received his bachelors from College of Emporia, Masters from the University of Kansas and his Ph.D. from University of California, Berkeley in 1938. Corson came to Cornell University in 1946 as an assistant professor of physics and helped to design the campus synchrotron. He was later promoted to professor in 1956, was named chairman of the physics department, and went on to become dean of the College of Engineering in 1959. | |
Dirk Coster | October 5th 1889 - February 12th 1950 |
Bernard Courtois | February 12th 1777 - September 27th 1838 |
Adair Crawford | 1748 - 1795 |
Baron Axel Fredrik Cronstedt | 1722 - 1765 |
Sir William Crookes | June 17th 1832 - April 4th 1919 |
Crookes studied at the Royal College of Chemistry in his native city of London, under August von Hofmann (1848). After working at the Radcliffe Observatory, Oxford, and the Chester College of Science, he returned to London in 1856, where, having inherited a large fortune, he edited Chemical News and spent his time on research. | | Following the invention of the spectroscope by Robert Bunsen and Gustav Kirchhoff, Crookes discovered the element thallium (1861) by means of its spectrum. In investigating the properties and molecular weight of thallium, he noticed unusual effects in the vacuum balance that he was using. This led him to investigate effects at low pressure and eventually to invent the instrument known as the Crookes radiometer (1875). This device is a small evacuated glass bulb containing an arrangement of four light metal vanes. Alternate sides of the vanes are polished and blackened. When radiant heat falls on the instrument, the vanes rotate. The effect depends on the low pressure of gas in the bulb; molecules leaving the dark (hotter) surfaces have greater momentum than those leaving the bright (cooler) surfaces. Although the instrument had little practical use, it was important evidence for the kinetic theory of gases. | | Crookes went on to investigate electrical discharges in gases at low pressure, producing an improved vacuum tube (the Crookes tube). He also investigated cathode rays and radioactivity. Crookes glass is a type of glass invented to protect the eyes of industrial workers from intense radiation. | | From about 1870, Crookes became interested in spiritualism and became one of the leading investigators of psychic phenomena. | |
Marie Curie (Marya Sklodowska) | November 7th 1867 - July 4th 1934 |
Pierre Curie | (May 15th 1859 - April 19th 1906 |
Pierre Curie was the son of a Paris physician. He was educated at the Sorbonne where he became an assistant in 1878. In 1882 he was made laboratory chief at the School of Industrial Physics and Chemistry where he remained until he was appointed professor of physics at the Sorbonne in 1904. In 1895 he married Marie Sklodowska, with whom he conducted research into the radioactivity of radium and with whom he shared the Nobel Prize for physics in 1903. | | His scientific career falls naturally into two periods, the time before the discovery of radioactivity by Henri Becquerel, when he worked on magnetism and crystallography, and the time after when he collaborated with his wife Marie Curie on this new phenomenon. | | In 1880 with his brother Jacques he had discovered piezoelectricity. 'Piezo' comes from the Greek for 'to press' and refers to the fact that certain crystals when mechanically deformed will develop opposite charges on opposite faces. The converse will also happen; i.e. an electric charge applied to a crystal will produce a deformation. The brothers used the effect to construct an electrometer to measure small electric currents. Marie Curie later used the instrument to investigate whether radiation from substances other than uranium would cause conductivity in air. Pierre Curie's second major discovery was in the effect of temperature on the magnetic properties of substances, which he was studying for his doctorate. In 1895 he showed that at a certain temperature specific to a substance it will lose its ferromagnetic properties; this critical temperature is now known as the Curie point. | | Shortly after this discovery he began to work intensively with his wife on the new phenomenon of radioactivity. Two new elements, radium and polonium, were discovered in 1898. The rays these elements produced were investigated and enormous efforts were made to produce a sample of pure radium. | | He received little recognition in his own country. He was initially passed over for the chairs of physical chemistry and mineralogy in the Sorbonne and was defeated when he applied for membership of the Academie in 1902. He was however later admitted in 1905. The only reason he seems eventually to have been given a chair (in 1904) was that he had been offered a post in Geneva and was seriously thinking of leaving France. Partly this may have been because his political sympathies were very much to the left and because he was unwilling to participate in the science policies of the Third Republic. | | Pierre Curie was possibly one of the first to suffer from radiation sickness. No attempts were made in the early days to restrict the levels of radiation received. He died accidentally in 1906 in rather strange circumstances - he slipped while crossing a Paris street, fell under a passing horse cab, and was kicked to death. The unit of activity of a radioactive substance, the curie, was named for him in 1910. | | The Curies' daughter Irene Joliot-Curie carried on research in radioactivity and also received the Nobel Prize for work done with her husband Frederic. | |
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John Dalton | September 6th 1766 - July 27th 1844 |
John Dalton was an English chemist, meteorologist and physicist. He is best known for his pioneering work in the development of modern atomic theory, and his research into colour blindness. | | In 1800 he became a secretary of the Manchester Literary and Philosophical Society, and in the following year he orally presented an important series of papers, entitled "Experimental Essays" on the constitution of mixed gases; on the pressure of steam and other vapours at different temperatures, both in a vacuum and in air; on evaporation; and on the thermal expansion of gases. These four essays were published in the Memoirs of the Lit snd Phil in 1802. | | The most important of all Dalton's investigations are those concerned with the atomic theory in chemistry, with which his name is inseparably associated. | | In his first published table of relative atomic weights six elements appear in this table, namely hydrogen, oxygen, nitrogen, carbon, sulfur, and phosphorus, with the atom of hydrogen conventionally assumed to weigh 1. Dalton provided no indication in this first paper how he had arrived at these numbers. However, in his laboratory notebook under the date 6 September 1803 there appears a list in which he sets out the relative weights of the atoms of a number of elements, derived from analysis of water, ammonia, carbon dioxide, etc. by chemists of the time. | | Despite the uncertainty at the heart of Dalton's atomic theory, the principles of the theory survived. To be sure, the conviction that atoms cannot be subdivided, created, or destroyed into smaller particles when they are combined , separated, or rearranged in chemical reactions is inconsistent with the existence of nuclear fusion and nuclear fission, but such processes are nuclear reactions and not chemical reactions. In addition, the idea that all atoms of a given element are identical in their physical and chemical properties is not precisely true, as we now know that different isotopes of an element have slightly varying weights. However, Dalton had created a theory of immense power and importance. Indeed, Dalton's innovation was fully as important for the future of the science as Antoine Laurent Lavoisier's oxygen-based chemistry had been. | |
Sir Humphry Davy | December 17th 1778 - May 29th 1829 |
Davy was born on December 17, 1778 in Penzance, Cornwall, England. He received his education in Penzance and in Truro. His father died in 1794, and Davy, in an effort to help support his family, became an apprentice to a surgeon-apothecary, J. Binghan Borlase. After reading Antoine Lavoisier's Traite Elementaire , Davy in 1797 became interested in chemistry. When Davy was released from his indenture as a apprentice, he became superintendent of the Medical Pneumatic Institution of Bristol. This organization was devoted to the study of the medical value of various gases, and it was here that Davy first made his reputation. He studied the oxides of nitrogen and discovered the physiological effects of nitrous oxide, which became known as laughing gas. He "breathed 16 quarts of the gas in seven minutes" and became "completely intoxicated" with it. It would be forty-five years later before nitrous oxide would be used as a anesthetic by dentists. From a notebook that he kept at this time are analytical results that document the discovery of nitrous oxide and that illustrate the law of multiple proportions: | | "When two elements combine and form more than one compound, the masses of one element that react with a fixed mass of the other are in the ratio of small whole numbers." | | In 1799, Davy did an experiment which showed that when two pieces of ice (or other substance with a low melting point) were rubbed together they could be melted without any other addition of heat. This experiment provided evidence that helped to disprove the caloric theory of heat. | | In 1802, Thomas Wedgwood in cooperation with Sir Humphry Davy published a paper entitled "An Account of a Method of Copying Paintings on Glass, and Making Profiles, by the Agency of Light upon Nitrates of Silver". The pictures made by this process were very temporary. As soon as the negatives were removed the pictures turned black. | | Davy was knighted in 1812. Three days after being knighted, he married a rich widow, Jan Apreece. Davy along with his wife and his assistant, Michael Faraday, toured Europe from 1813 to 1815. Upon their return to England, Davy invented his miner's safety helmet. The lamp of this safety helmet would burn safely and emit light even when there was an explosive mixture of methane and air present. Davy did not patent the lamp. This error lead to later false claims by locomotive engineer George Stephenson that it was he that invented the miner's safety helmet, not Davy. | | In 1825, Hans Christian Oersted first successfully isolated aluminium in a pure form. Sir Humphry Davy had previously been unsuccessful at such attempts. It was Davy who named the element "aluminum", the name used in the United States. The rest of the world uses the term "aluminium". | | Among Davy's other accomplishments are the introduction of a chemical approach to agriculture and the tanning and mineralogy industries. He designed an Arc Lamp and invented a process that could be used to desalinate sea water. He also designed a method whereby copper-clad ships could be protected by having zinc plates connected to them. | | In 1827, Davy became seriously ill. The illness was later attributed to his inhalation of many gases over the years. In 1829 he made his home in Rome. While in Rome, he had a heart attack and he later died on May 29, 1829 in Geneva, Switzerland. | | Davy's qualitative work was excellent but this could not always be said for his quantitative work. He was quick to make decisions and easily distracted. In his life time he went after many honors and won many of them. He had great perception, was good in the laboratory, but was very erratic at times. | |
Andre Louis Debierne | July 14th 1874 - August 31st 1949 |
Born in Paris, France, Debierne was educated at the Ecole de Physique et Chemie. After graduation he worked at the Sorbonne and as an assistant to Pierre and Marie Curie, finally succeeding the latter as director of the Radium Institute. On his retirement in 1949 he in turn was succeeded by Marie Curie's daughter, Irene Joliot-Curie. | | Debierne was principally a radiochemist; his first triumph came in 1900 with the discovery of a new radioactive element, actinium, which he isolated while working with pitchblende. In 1905 he went on to show that actinium, like radium, formed helium. This was of some significance in helping Ernest Rutherford to appreciate that some radioactive elements decay by emitting an alpha particle (or, as it turned out to be, the nucleus of a helium atom). In 1910, in collaboration with Marie Curie, he isolated pure metallic radium. | |
Eugene-Antole Demarcay | January 1st 1852 - December 1904 |
Arthur Jeffrey Dempster | August 14th 1886 - March 11th 1950 |
Friedrich Ernst Dorn | July 27th 1848 - December 16th 1916 |
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Anders Gustaf Ekeberg | January 16th 1767 - February 11th 1813 |
Juan Jose Elhuyar | (June 15th 1754 - September 20th 1796 |
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(Gabriel) Daniel Fahrenheit | May 24th 1686 - September 16th 1736 |
Michael Faraday | September 22nd 1791 - August 25th 1867 |
An English chemist and physicist (or natural philosopher, in the terminology of that time) who contributed significantly to the fields of electromagnetism and electrochemistry. He established that magnetism could affect rays of light and that there was an underlying relationship between the two phenomena. | | Some historians of science refer to him as the best experimentalist in the history of science. It was largely due to his efforts that electricity became viable for use in technology. The SI unit of capacitance, the farad, is named after him, as is the Faraday constant, the charge on a mole of electrons (about 96,485 coulombs). Faraday's law of induction states that a magnetic field changing in time creates a proportional electromotive force. | | Michael Faraday was born in Newington Butts, near present-day Elephant and Castle in South London, England. His family was poor; his father, James Faraday, was a Yorkshire blacksmith who suffered ill-health throughout his life. Therefore, Faraday had to educate himself. At fourteen he became apprenticed to a local bookbinder and seller George Riebau and, during his seven-year apprenticeship, read many books, developing an interest in science and specifically electricity. In particular, he was inspired by the book Conversations in Chemistry by Jane Marcet. | | At the age of twenty, in 1812, at the end of his apprenticeship, Faraday attended lectures by the eminent English chemist and physicist Humphry Davy of the Royal Institution and Royal Society, and John Tatum, founder of the City Philosophical Society. The tickets were given to Faraday by William Dance (one of the founders of the Royal Philharmonic Society). Afterwards, Faraday sent Davy a sample of his notes taken during the lectures. Davy's reply was immediate, kind and favorable. When Davy damaged his eyesight in an accident with nitrogen trichloride, he decided to employ Faraday as a secretary. When John Payne, one of the Royal Institution's assistants, was sacked, the now Sir Humphry Davy was asked to find a replacement, and he appointed Faraday as Chemical Assistant at the Royal Institution on 1 March 1813. | | Faraday worked extensively in the field of chemistry, discovering chemical substances such as benzene (which he called bicarburet of hydrogen), inventing the system of oxidation numbers, and liquefying gases such as chlorine. He prepared the first clathrate hydrate. Faraday also discovered the laws of electrolysis and popularized terminology such as anode, cathode, electrode, and ion, terms largely created by William Whewell. For these accomplishments, many modern chemists regard Faraday as one of the finest experimental scientists in history. | | His greatest work was with electricity. The first experiment which he recorded was the construction of a voltaic pile with seven halfpence pieces, stacked together with seven disks of sheet zinc, and six pieces of paper moistened with salt water. In his work on static electricity, Faraday demonstrated that the charge only resided on the exterior of a charged conductor, and exterior charge had no influence on anything enclosed within a conductor. This is because the exterior charges redistribute such that the interior fields due to them cancel. This shielding effect is used in what is now known as a Faraday cage. |
Enrico Fermi | (September 29th 1901 - November 28th 1954 |
American physicist, born in Italy. He studied at Pisa, Gottingen, and Leiden, and taught physics at the universities of Florence and Rome. He contributed to the early theory of beta decay and the neutrino and to quantum statistics. For his experiments with neutrons he was awarded the 1938 Nobel Prize in Physics. Fermi's wife, Laura, was Jewish, and the family did not return to Fascist Italy after the journey to Stockholm to receive the Nobel award, but continued on to the United States. Fermi was professor of physics at Columbia Univ. (1939-45) and at the Univ. of Chicago (1946-54). He created the first self-sustaining chain reaction in uranium at Chicago in 1942 and worked on the atomic bomb at Los Alamos. Later he contributed to the development of the hydrogen bomb and served on the General Advisory Committee of the Atomic Energy Commission, which named him to receive its first special award ($25,000) shortly before his death. Fermi was outstanding as an experimenter, theorist, and teacher. He wrote Elementary Particles (1951). | | In 1954 the chemical element fermium of atomic number 100 was named for him. Publication of his Collected Papers (ed. by Edoardo Amaldi et al.) was begun in 1962. 1 See L. Fermi, Atoms in the Family (1954, repr. 1988); biography by E. Segre (1970). | |
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Johan Gadolin | (June 5th 1760 - August 15th 1852 |
Johan Gottlieb Gahn | 1745 - 1818 |
Joseph Louis Gay-Lussac | December 6th 1778 - May 9th 1850 |
Joseph Louis Gay-Lussac, by virtue of his skill and diligence as an experimentalist, and by his demonstration of the power of the scientific method, deserves recognition as a great scientist. Born on December 6, 1778, Joseph was the eldest of five children. His father, Antoine Gay, was a lawyer who, to distinguish himself from other people in the Limoges region with the last name of Gay, used the surname Gay-Lussac from the name of some family property near St Leonard. The French Revolution affected many of what were to become the French scientific elite. Gay-Lussac was sent to Paris at the age of fourteen when his father was arrested. After having had private lessons and attending a boarding school, the Ecole Polytechnique and the civil engineering school, Gay-Lussac became an assistant to Berthollet who was himself a co-worker of Lavoisier. Gay-Lussac thus got the chance to become part of the group of famous men who spent time at Berthollet's country house near Arcueil. Here among the Arcueil Society he received his training in chemical research. | | With the encouragement of Berthollet and LaPlace, Gay-Lussac at the age of 24 conducted his first major research in the winter of 1801-1802. He settled some conflicting evidence about the expansion properties of different gases. By excluding water vapour from the apparatus and by making sure that the gases themselves were free of moisture, he obtained results that were more accurate than had been obtained previously by others. He concluded that equal volumes of all gases expand equally with the same increase in temperature. While Jacques Charles discovered this volume-temperature relationship fifteen years earlier, he had not published it. Unlike Gay-Lussac, Charles did not measure the coefficient of expansion. Also, because of the presence of water in the apparatus and the gases themselves, Charles obtained results that indicated unequal expansion for the gases that were water soluble. | | Gay-Lussac, like his mentor Berthollet, was interested in how chemical reactions take place. Working with the mathematical physicist, LaPlace, Gay-Lussac made quantitative measurements on capillary action. The goal was to support LaPlace 's belief in his Newtonian theory of chemical affinity. In 1814 this theoretical bent continued as Gay-Lussac and LaPlace sought to determine if chemistry could be reduced to applied mathematics. The approach was to ask whether the conditions of chemical reactions could be reduced simply to, as LaPlace had suggested, considerations of heat. | | As with his mentor before him, Gay-Lussac was consulted by industry and supported by the government. "Napoleonic science sharpened the appetites of young men by holding up the prospects of recognition and reward". Gay-Lussac and Thenard, the laboratory boy turned professor, isolated the element boron nine days before Davy'sroup did (but Davyas the first to publish.) Gay-Lussac led his group into the isolation of plant alkaloids for potential medical use and he was instrumental in developing the industrial production of oxalic acid from the fusion of sawdust with alkali. His most important contribution to industry was, in 1827, the refinement of the lead chamber process for the production of sulfuric acid, the industrial chemical produced in largest volume in the world. | | While Gay-Lussac was a great theoretical scientist, he was also respected by his colleagues for his careful, elegant, experimental work. Wanting to know why and how something happened was important to Gay-Lussac, but he preferred knowing much about a limited subject rather than proposing broad new theories which might be wrong . He devised many new types of apparatus such as the portable barometer, an improved pipette and burette and, when working at the Mint, a new apparatus for quickly and accurately estimating the purity of silver which was the only legal measure in France until 1881. His work on iodine is considered a model of chemical research. His precise measurement of the thermal expansion of gases mentioned above was used by Lord Kelvin in the development of the absolute temperature scale and Third Law of Thermodynamics and by Clausius in the development of the Second Law. He and Thenard improved existing methods of elemental analysis and developed volumetric procedures for measuring acids and alkalis. His quantification of the effect of light on the reaction of chlorine with hydrogen elevated photochemistry from mere artifice into a theoretical science which culminated, fifty years after his death, in the quantum theory. An example of his dedication to meticulous experimenting is his decision to undertake a balloon flight to a record setting height of 23,000 feet to test an hypotheses on earth's magnetic field and the composition of the air. | |
Albert Ghiorso | July 15th 1915 |
An American nuclear scientist who helped discover several chemical elements on the periodic table. | | He was born in Vallejo, California and grew up in Alameda, California. As a teenager, he built radio circuitry and earned a reputation for reaching radio frequency distances that outdid the military. | | He received his bachelor's degree in electrical engineering from the University of California, Berkeley in 1937. After graduation, he worked for a company that produced emergency communication devices, and invented the world's first commercial Geiger counter, which evolved into his participation in the Manhattan Project. | | He was introduced to Glenn T. Seaborg through a mutual friendship between their wives who also worked as secretaries at the Berkeley Radiation Laboratory. | | Seaborg and Ghiorso's collaboration was most fruitful in the early days of the cyclotron, when its reuslts were hard to identify and detect. Their work resulted in many elements being discovered at UC Berkeley, and Ghiorso is credited with having co-discovered the following elements: | | Americium around 1945, Curium in 1944, Berkelium in 1949, Californium in 1950, Einsteinium in 1952, Fermium in 1953, Mendelevium in 1955, Nobelium in 1958-59, Lawrencium in 1961, Rutherfordium in 1969, Hahnium in 1970 and Seaborgium in 1974. | |
William Gregor | December 25th 1761 - June 11th 1817 |
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Otto Hahn | March 8th 1879 - July 28ht 1968 |
Charles Hatchett | January 2nd 1765 - March 10th 1847 |
An English chemist who discovered the element niobium. | | In 1801 while working for the British Museum in London he analyzed a piece of columbite in the museum's collection. Columbite turned out to be a very complex mineral, but Hachett discovered that it contained a "new earth" which implied the existence of a new element. Hatchett called this element columbium (Cb). On November 26th of that year he announced his discovery of columbium before the Royal Society. | | The element was later rediscovered and renamed as current niobium (the current name). Later in life he quit his job as a chemist in order to devote his full time to making money by working at his family's coach fabrication business. | | The Institute of Materials (London) has been awarding the Charles Hatchett Award yearly to noted chemists since 1979. The award is given to the "author of the best paper on the science and technology of niobium and its alloys." | |
George Charles de Hevesy | August 1st 1885 - July 5th 1966 |
Wilhelm von Hisinger | 1766 - 1852 |
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